Shanxian Chemical
SUPPLEMENTS
70 Hydrogen Peroxide Sds
Seventy hydrogen peroxide safety data table
1. Chemicals and company identification
This product is seventy (70%) concentration of hydrogen peroxide, that is, hydrogen peroxide solution. Manufacturer [specific company name], contact information [detailed contact information].
2. Component/composition information
Main ingredients: hydrogen peroxide ($H_2O_2 $), content of 70%.
3. Overview of hazards
1. ** Physical and chemical hazards **: Strong oxidizing, mixed with combustible materials can easily form explosive mixtures, in case of open flame, high heat can cause combustion and explosion.
2. ** Health hazards **: Inhalation of the product vapor or fog has strong irritation to the respiratory tract. Direct eye contact with liquids can cause irreversible damage or even blindness. Abdominal pain, chest pain, breathing difficulties, vomiting, temporary motor and sensory disturbances, elevation of body temperature, etc. occur in oral poisoning. Visual impairment, epileptic spasm, and light paralysis occur in individual cases. Long-term exposure to this product can cause contact dermatitis.
IV. First aid measures
1. ** Skin contact **: Immediately remove contaminated clothing and rinse with plenty of flowing water for 20 to 30 minutes. If there is any discomfort, seek medical attention.
2. ** Eye contact **: Immediately lift the eyelids and rinse thoroughly with plenty of flowing water or normal saline for 10 to 15 minutes. If there is any discomfort, seek medical attention.
3. ** Inhalation **: Quickly leave the scene to a fresh place in the air. Keep the respiratory tract unobstructed. If breathing difficulties, give oxygen. Breathing and heartbeat stop, and immediately carry out cardiopulmonary resuscitation. Seek medical attention.
4. ** Ingestion **: Drink enough warm water to induce vomiting. Seek medical attention.
5. Fire protection measures
1. ** Hazardous characteristics **: Explosive strong oxidizing agent. Hydrogen peroxide itself is non-flammable, but it can react with combustibles to release a lot of heat and oxygen to cause fire and explosion. Hydrogen peroxide is most stable when the pH is 3.5~ 4.5, and it is easily decomposed in alkaline solutions. It can also decompose when exposed to strong light, especially short-wave radiation. When heated to above 100 ° C, it begins to decompose sharply. It forms an explosive mixture with many organic substances such as sugar, starch, alcohols, petroleum products, etc., and can explode under the action of impact, heat or electric sparks. Hydrogen peroxide rapidly decomposes after contact with many inorganic compounds or impurities and causes an explosion, releasing a large amount of heat, oxygen and water vapor. Most heavy metals (such as iron, copper, silver, lead, mercury, zinc, cobalt, nickel, chromium, manganese, etc.) and their oxides and salts are active catalysts, and dust, cigarette ash, toner, rust, etc. can also accelerate decomposition. Hydrogen peroxide with a concentration of more than 69% can produce a gas phase explosion in a closed container with a suitable ignition source or temperature.
2. ** Hazardous Combustion Products **: Oxygen, Water.
3. ** Fire Extinguishing Methods **: Firefighters must wear full-body fire and toxin suits and extinguish the fire in the upwind direction. Move the container from the fire to an open place as much as possible. Spray water to keep the fire container cool until the fire is over. If the container in the fire field has changed color or produces sound from the safety pressure relief device, it must be evacuated immediately. Fire Extinguishing Agent: Water, Mist Water, Dry Powder, Sand.
6. Emergency Treatment for Leaks
1. ** Emergency Treatment **: Quickly evacuate personnel from the leaked contaminated area to a safe area, and isolate them, strictly restricting access. It is recommended that emergency personnel wear self-contained positive pressure breathing apparatus and anti-toxic clothing. Cut off the source of leakage as much as possible. Prevent flow into restricted spaces such as sewers and flood drains.
2. ** Small leaks **: Absorb with sand, vermiculite or other inert materials. It can also be rinsed with a large amount of water, and then diluted into the wastewater system after washing water.
3. ** Large leaks **: Build a dike or dig a pit for containment. Spray-like water cools and dilutes steam, protects site personnel, and dilutes leaks into non-combustible materials. Transfer to a tanker or special collector by pump, and recycle or transport to a waste treatment site for disposal.
VII. Operational disposal and storage
1. ** Operation Precautions **: Closed operation, full ventilation. Operators must be specially trained and strictly abide by the operating procedures. It is recommended that operators wear self-priming filter gas masks (full masks), polyethylene gas suits, and neoprene gloves. Keep away from fire and heat sources. Smoking is strictly prohibited in the workplace. Keep away from flammable and combustible materials. Prevent steam leakage into the air of the workplace. Avoid contact with reducing agents and active metal powders. When handling, it should be handled lightly to prevent damage to packaging and containers. Equipped with corresponding varieties and quantities of fire-fighting equipment and leakage emergency treatment equipment. Empty containers may remain harmful substances.
2. ** Storage Precautions **: Store in a cool and ventilated warehouse. Keep away from fire and heat sources. The storage temperature should not exceed 30 ° C. Keep the container sealed. It should be stored separately from easy (available) combustibles, reducing agents, active metal powders, etc., and should not be mixed. The storage area should be equipped with leakage emergency treatment equipment and suitable containment materials.
VIII. Contact control/personal protection
1. ** Occupational exposure limits **: China MAC (mg/m ³): No standard has been established; former Soviet Union MAC (mg/m ³): 1.
2. ** Monitoring methods **: No information.
3. ** Engineering control **: The production process is closed and fully ventilated. Safe shower and eye washing equipment is provided.
4. ** Respiratory system protection **: When possible exposure to its vapors, a self-priming filter gas mask (full mask) should be worn.
5. ** Eye protection **: Protection has been made in respiratory system protection.
6. ** Body protection **: Wear polyethylene gas suit.
7. ** Hand protection **: Wear neoprene gloves.
8. ** Other protection **: Smoking is strictly prohibited at the work site. After work, shower and change clothes. Pay attention to personal cleanliness and hygiene.
9. Physical and chemical characteristics
1. ** Appearance and characteristics **: Colorless and transparent liquid with a faint special smell.
2. ** pH **: No data available.
3. ** Melting point (℃)**: - 0.43.
4. ** Boiling point (℃)**: 150.2.
5. ** Relative density (water = 1) **: 1.46 (20 ° C).
6. ** Relative vapor density (air = 1) **: No data available.
7. ** Saturated vapor pressure (kPa) **: 0.13 (15.3 ° C).
8. ** Heat of combustion (kJ/mol) **: No meaning.
9. ** Critical temperature (℃)**: No information available.
10. ** Critical pressure (MPa) **: No information available.
11. ** Octanol/water partition coefficient **: No information available.
12. ** Flash point (℃)**: meaningless.
13. ** Ignition temperature (℃)**: meaningless.
14. ** Upper limit of explosion [% (V/V) ] **: meaningless.
15. ** Lower limit of explosion [% (V/V) ] **: meaningless.
16. ** Solubility **: soluble in water, alcohol, ether, insoluble in benzene, petroleum ether.
X, stability and reactivity
1. ** Stability **: unstable, easily decomposed by heat or in contact with organic matter.
2. ** Prohibited ingredients **: flammable or flammable substances, strong reducing agents, active metal powders, bases, alcohols, amines.
3. ** Conditions to avoid contact **: heat, light, contact with metals and their salts.
4. ** Polymerization hazards **: No polymerization.
5. ** Decomposition products **: oxygen, water.
XI. Toxicological data
1. ** Acute toxicity **: $LD_ {50} $: no data; $LC_ {50} $: 406ppm (rat inhalation).
2. ** Irritation **: Rabbit transocular: 100mg, severe irritation. Rabbit transdermal: open irritation test, 360mg, mild irritation.
XII. Ecological data
1. ** Ecotoxicity **: no data.
2. ** Biodegradability **: no data.
3. ** Non-biodegradability **: no data.
4. ** Other Harmful Effects **: The substance may be hazardous to the environment, and special attention should be paid to water bodies.
13. Waste Disposal
1. ** Nature of Waste **: Hazardous Waste.
2. ** Waste Disposal Method **: Disposal by Controlled Incineration. If possible, reuse the container or bury it in the specified place.
3. ** Waste Precautions **: Refer to relevant national and local regulations before disposal. Return the emptied container to the manufacturer or bury it in the specified place.
14. Transportation Information
1. ** Dangerous Goods Number **: 51001.
2. ** UN No. **: 2015.
3. ** Packing Marks **: Oxidants; Corrosive Products.
4. ** Packing Category **: Class I Packing.
5. ** Packing Method **: Small-opening plastic drums; ordinary wooden boxes or half-lattice wooden boxes outside glass bottles or plastic drums (cans); ordinary wooden boxes outside frosted-mouth glass bottles or threaded-mouth glass bottles; ordinary wooden boxes outside ampoules; ordinary wooden boxes outside threaded-mouth glass bottles, iron-capped pressure-mouth glass bottles, plastic bottles or metal drums (cans).
6. ** Transportation Precautions **: During railway transportation, it should be assembled in strict accordance with the dangerous goods assembly table in the "Dangerous Goods Transportation Rules" of the Ministry of Railways. When transporting, it should be shipped separately. During transportation, it is necessary to ensure that the container does not leak, collapse, fall or damage. It is strictly forbidden to mix with acids, flammable substances, organic substances, reducing agents, self-igniting items, and flammable items in case of moisture. During transportation, the speed of the vehicle should not be too fast, and it is not allowed to forcibly overtake. When transporting by road, it should be driven according to the specified route. Before and after loading and unloading of transportation vehicles, they should be thoroughly cleaned and cleaned. It is strictly forbidden to mix organic substances, flammable substances and other impurities.
XV. Regulatory Information
Regulations on the Safety Management of Chemical Dangerous Substances (promulgated by the State Council on February 17, 1987), Implementing Regulations on the Safety Management of Chemical Dangerous Substances (Hua Laofa [1992] No. 677), Regulations on the Safe Use of Chemicals in the Workplace ([1996] Labor Ministry No. 423) and other regulations have made corresponding provisions for the safe use, production, storage, transportation, loading and unloading of chemical dangerous goods; the classification and marking of commonly used hazardous chemicals (GB 13690-92) classifies the substance as Class 5.1 oxidant.
1. Chemicals and company identification
This product is seventy (70%) concentration of hydrogen peroxide, that is, hydrogen peroxide solution. Manufacturer [specific company name], contact information [detailed contact information].
2. Component/composition information
Main ingredients: hydrogen peroxide ($H_2O_2 $), content of 70%.
3. Overview of hazards
1. ** Physical and chemical hazards **: Strong oxidizing, mixed with combustible materials can easily form explosive mixtures, in case of open flame, high heat can cause combustion and explosion.
2. ** Health hazards **: Inhalation of the product vapor or fog has strong irritation to the respiratory tract. Direct eye contact with liquids can cause irreversible damage or even blindness. Abdominal pain, chest pain, breathing difficulties, vomiting, temporary motor and sensory disturbances, elevation of body temperature, etc. occur in oral poisoning. Visual impairment, epileptic spasm, and light paralysis occur in individual cases. Long-term exposure to this product can cause contact dermatitis.
IV. First aid measures
1. ** Skin contact **: Immediately remove contaminated clothing and rinse with plenty of flowing water for 20 to 30 minutes. If there is any discomfort, seek medical attention.
2. ** Eye contact **: Immediately lift the eyelids and rinse thoroughly with plenty of flowing water or normal saline for 10 to 15 minutes. If there is any discomfort, seek medical attention.
3. ** Inhalation **: Quickly leave the scene to a fresh place in the air. Keep the respiratory tract unobstructed. If breathing difficulties, give oxygen. Breathing and heartbeat stop, and immediately carry out cardiopulmonary resuscitation. Seek medical attention.
4. ** Ingestion **: Drink enough warm water to induce vomiting. Seek medical attention.
5. Fire protection measures
1. ** Hazardous characteristics **: Explosive strong oxidizing agent. Hydrogen peroxide itself is non-flammable, but it can react with combustibles to release a lot of heat and oxygen to cause fire and explosion. Hydrogen peroxide is most stable when the pH is 3.5~ 4.5, and it is easily decomposed in alkaline solutions. It can also decompose when exposed to strong light, especially short-wave radiation. When heated to above 100 ° C, it begins to decompose sharply. It forms an explosive mixture with many organic substances such as sugar, starch, alcohols, petroleum products, etc., and can explode under the action of impact, heat or electric sparks. Hydrogen peroxide rapidly decomposes after contact with many inorganic compounds or impurities and causes an explosion, releasing a large amount of heat, oxygen and water vapor. Most heavy metals (such as iron, copper, silver, lead, mercury, zinc, cobalt, nickel, chromium, manganese, etc.) and their oxides and salts are active catalysts, and dust, cigarette ash, toner, rust, etc. can also accelerate decomposition. Hydrogen peroxide with a concentration of more than 69% can produce a gas phase explosion in a closed container with a suitable ignition source or temperature.
2. ** Hazardous Combustion Products **: Oxygen, Water.
3. ** Fire Extinguishing Methods **: Firefighters must wear full-body fire and toxin suits and extinguish the fire in the upwind direction. Move the container from the fire to an open place as much as possible. Spray water to keep the fire container cool until the fire is over. If the container in the fire field has changed color or produces sound from the safety pressure relief device, it must be evacuated immediately. Fire Extinguishing Agent: Water, Mist Water, Dry Powder, Sand.
6. Emergency Treatment for Leaks
1. ** Emergency Treatment **: Quickly evacuate personnel from the leaked contaminated area to a safe area, and isolate them, strictly restricting access. It is recommended that emergency personnel wear self-contained positive pressure breathing apparatus and anti-toxic clothing. Cut off the source of leakage as much as possible. Prevent flow into restricted spaces such as sewers and flood drains.
2. ** Small leaks **: Absorb with sand, vermiculite or other inert materials. It can also be rinsed with a large amount of water, and then diluted into the wastewater system after washing water.
3. ** Large leaks **: Build a dike or dig a pit for containment. Spray-like water cools and dilutes steam, protects site personnel, and dilutes leaks into non-combustible materials. Transfer to a tanker or special collector by pump, and recycle or transport to a waste treatment site for disposal.
VII. Operational disposal and storage
1. ** Operation Precautions **: Closed operation, full ventilation. Operators must be specially trained and strictly abide by the operating procedures. It is recommended that operators wear self-priming filter gas masks (full masks), polyethylene gas suits, and neoprene gloves. Keep away from fire and heat sources. Smoking is strictly prohibited in the workplace. Keep away from flammable and combustible materials. Prevent steam leakage into the air of the workplace. Avoid contact with reducing agents and active metal powders. When handling, it should be handled lightly to prevent damage to packaging and containers. Equipped with corresponding varieties and quantities of fire-fighting equipment and leakage emergency treatment equipment. Empty containers may remain harmful substances.
2. ** Storage Precautions **: Store in a cool and ventilated warehouse. Keep away from fire and heat sources. The storage temperature should not exceed 30 ° C. Keep the container sealed. It should be stored separately from easy (available) combustibles, reducing agents, active metal powders, etc., and should not be mixed. The storage area should be equipped with leakage emergency treatment equipment and suitable containment materials.
VIII. Contact control/personal protection
1. ** Occupational exposure limits **: China MAC (mg/m ³): No standard has been established; former Soviet Union MAC (mg/m ³): 1.
2. ** Monitoring methods **: No information.
3. ** Engineering control **: The production process is closed and fully ventilated. Safe shower and eye washing equipment is provided.
4. ** Respiratory system protection **: When possible exposure to its vapors, a self-priming filter gas mask (full mask) should be worn.
5. ** Eye protection **: Protection has been made in respiratory system protection.
6. ** Body protection **: Wear polyethylene gas suit.
7. ** Hand protection **: Wear neoprene gloves.
8. ** Other protection **: Smoking is strictly prohibited at the work site. After work, shower and change clothes. Pay attention to personal cleanliness and hygiene.
9. Physical and chemical characteristics
1. ** Appearance and characteristics **: Colorless and transparent liquid with a faint special smell.
2. ** pH **: No data available.
3. ** Melting point (℃)**: - 0.43.
4. ** Boiling point (℃)**: 150.2.
5. ** Relative density (water = 1) **: 1.46 (20 ° C).
6. ** Relative vapor density (air = 1) **: No data available.
7. ** Saturated vapor pressure (kPa) **: 0.13 (15.3 ° C).
8. ** Heat of combustion (kJ/mol) **: No meaning.
9. ** Critical temperature (℃)**: No information available.
10. ** Critical pressure (MPa) **: No information available.
11. ** Octanol/water partition coefficient **: No information available.
12. ** Flash point (℃)**: meaningless.
13. ** Ignition temperature (℃)**: meaningless.
14. ** Upper limit of explosion [% (V/V) ] **: meaningless.
15. ** Lower limit of explosion [% (V/V) ] **: meaningless.
16. ** Solubility **: soluble in water, alcohol, ether, insoluble in benzene, petroleum ether.
X, stability and reactivity
1. ** Stability **: unstable, easily decomposed by heat or in contact with organic matter.
2. ** Prohibited ingredients **: flammable or flammable substances, strong reducing agents, active metal powders, bases, alcohols, amines.
3. ** Conditions to avoid contact **: heat, light, contact with metals and their salts.
4. ** Polymerization hazards **: No polymerization.
5. ** Decomposition products **: oxygen, water.
XI. Toxicological data
1. ** Acute toxicity **: $LD_ {50} $: no data; $LC_ {50} $: 406ppm (rat inhalation).
2. ** Irritation **: Rabbit transocular: 100mg, severe irritation. Rabbit transdermal: open irritation test, 360mg, mild irritation.
XII. Ecological data
1. ** Ecotoxicity **: no data.
2. ** Biodegradability **: no data.
3. ** Non-biodegradability **: no data.
4. ** Other Harmful Effects **: The substance may be hazardous to the environment, and special attention should be paid to water bodies.
13. Waste Disposal
1. ** Nature of Waste **: Hazardous Waste.
2. ** Waste Disposal Method **: Disposal by Controlled Incineration. If possible, reuse the container or bury it in the specified place.
3. ** Waste Precautions **: Refer to relevant national and local regulations before disposal. Return the emptied container to the manufacturer or bury it in the specified place.
14. Transportation Information
1. ** Dangerous Goods Number **: 51001.
2. ** UN No. **: 2015.
3. ** Packing Marks **: Oxidants; Corrosive Products.
4. ** Packing Category **: Class I Packing.
5. ** Packing Method **: Small-opening plastic drums; ordinary wooden boxes or half-lattice wooden boxes outside glass bottles or plastic drums (cans); ordinary wooden boxes outside frosted-mouth glass bottles or threaded-mouth glass bottles; ordinary wooden boxes outside ampoules; ordinary wooden boxes outside threaded-mouth glass bottles, iron-capped pressure-mouth glass bottles, plastic bottles or metal drums (cans).
6. ** Transportation Precautions **: During railway transportation, it should be assembled in strict accordance with the dangerous goods assembly table in the "Dangerous Goods Transportation Rules" of the Ministry of Railways. When transporting, it should be shipped separately. During transportation, it is necessary to ensure that the container does not leak, collapse, fall or damage. It is strictly forbidden to mix with acids, flammable substances, organic substances, reducing agents, self-igniting items, and flammable items in case of moisture. During transportation, the speed of the vehicle should not be too fast, and it is not allowed to forcibly overtake. When transporting by road, it should be driven according to the specified route. Before and after loading and unloading of transportation vehicles, they should be thoroughly cleaned and cleaned. It is strictly forbidden to mix organic substances, flammable substances and other impurities.
XV. Regulatory Information
Regulations on the Safety Management of Chemical Dangerous Substances (promulgated by the State Council on February 17, 1987), Implementing Regulations on the Safety Management of Chemical Dangerous Substances (Hua Laofa [1992] No. 677), Regulations on the Safe Use of Chemicals in the Workplace ([1996] Labor Ministry No. 423) and other regulations have made corresponding provisions for the safe use, production, storage, transportation, loading and unloading of chemical dangerous goods; the classification and marking of commonly used hazardous chemicals (GB 13690-92) classifies the substance as Class 5.1 oxidant.
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