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  • Dipole Dipole vs Hydrogen Bonding Strength

Dipole Dipole vs Hydrogen Bonding Strength

On the comparison of dipole-dipole force and hydrogen bond strength
All things in the world, the intermolecular force has its own characteristics. Both the dipole-dipole force and the hydrogen bond are important forms of intermolecular interaction. However, the strength of the dipole-dipole force and the hydrogen bond is a question worthy of in-depth investigation.

The bipolar-dipole force exists between polar molecules. Polar molecules form positive and negative poles due to uneven charge distribution, just like yin and yang in the world. The positive electrode of this molecule and the negative electrode of another molecule attract each other, resulting in a dipole-dipole force. Although this force can maintain the relationship between molecules, its strength is relatively limited.

As for the hydrogen bond, the formation conditions are quite special. When a hydrogen atom covalently binds with an extremely electronegative atom (such as nitrogen, oxygen, and fluorine), the hydrogen atom becomes almost a "naked" proton. Due to its extremely high charge density, it can have a strong interaction with another highly electronegative atom, which is called a hydrogen bond. The strength of the hydrogen bond is usually stronger than the general dipole-dipole force. What do you mean? The formation of hydrogen bonds involves a special interaction between hydrogen atoms and highly electronegative atoms. This interaction is like a tight bond, which is stronger than the general dipole-dipole attraction.

Take water as an example (although no specific substance is mentioned, water is a common substance containing hydrogen bonds, which is convenient for explanation). Hydrogen binds to oxygen in water molecules, and hydrogen forms a hydrogen bond with the oxygen of adjacent water molecules. Many unique properties of water, such as higher boiling point and higher surface tension, are closely related to the existence of hydrogen bonds. If it is only an ordinary dipole-dipole force, it is difficult to make water have such properties. It can be seen that the strength of hydrogen bonds is stronger than that of dipole-dipole forces in many cases.

In summary, the hydrogen bond is stronger than the dipole-dipole force, which is of great significance for exploring the intermolecular interactions and the physical and chemical properties of matter.