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Hydrogen Peroxide Decomposition Mechanism

On the mechanism of decomposition of hydrogen peroxide
The decomposition of hydrogen peroxide is an important reaction in chemistry. It is of great significance to explore its mechanism.

Hydrogen peroxide ($H_2O_2 $) has a unique molecular structure and contains a peroxy bond ($-O - O - $). This bond has a high energy, which makes hydrogen peroxide active and easy to decompose.

The main ways of decomposition are thermal decomposition and catalytic decomposition. During thermal decomposition, due to the increase in temperature, the molecule is energized, the peroxy bond vibration intensifies, and eventually breaks. The reaction formula is as follows: $2H_2O_2\ stackrel {\ Delta }{=\!=\!=} 2H_2O + O_2 ↑ $. In this process, the peroxide bond is broken to form water and oxygen.

Catalytic decomposition is more common and efficient. Many substances can be used as catalysts, such as manganese dioxide ($MnO_2 $). When there is $MnO_2 $, hydrogen peroxide contacts it, and the active check point on the surface of $MnO_2 $adsorbs hydrogen peroxide molecules. Subsequently, a series of complex electron transfer and chemical bond rearrangements occur. $MnO_2 $Weakens the peroxide bond first, causing it to break and form intermediate products, such as $MnOOH $. Then, the intermediate product further reacts to regenerate $MnO_2 $, and releases water and oxygen. The mass and chemical properties of $MnO_2 $remain unchanged before and after the reaction, and continue to play a catalytic role.

Another enzyme catalyzes decomposition, and catalase in organisms can efficiently catalyze the decomposition of hydrogen peroxide. The structure of the active center of catalase is highly compatible with hydrogen peroxide molecules, which can specifically bind hydrogen peroxide, reduce the activation energy of the reaction, and make the decomposition reaction proceed rapidly under mild conditions to protect organisms from hydrogen peroxide.

The study of the decomposition mechanism of hydrogen peroxide helps us to deeply understand the essence of chemical reactions and lay a theoretical foundation for applications in many fields, such as chemical production, environmental protection, and biomedicine.